A NTUA Diploma Thesis titled “Critical factors of road users’ self declared behavior and safety in Greece” was recently presented by Konstantina-Aikaterini Mavraki. To achieve this objective, critical behaviours were analysed, such as compliance with speed limits, seat belt use, alcohol consumption, mobile phone use, etc., across different categories of users, including car drivers, motorcyclists, cyclists, pedestrians, and users of electric scooters. The analysis was carried out using descriptive statistics and binary logistic regression, with six separate models for different categories of road network users, utilizing also the results of the ESRA survey, which were compared with field measurement data in order to highlight differences between self-reported and observed behaviour. The findings suggest that individuals who agree with and accept risky and illegal road behaviours are more likely to commit violations of the Road Traffic Code across all examined categories of road users. Furthermore, recommendations that could enhance road users’ safety, such as educational and training campaigns and targeted infrastructure interventions were provided.